2007, Vol.10, No.3, pp.207-217
An analytical model has been elaborated for the description of
orientational relaxation in hydrogen-bonding liquids beyond the
first cumulant approximation. The orientational correlation
functions are uniquely determined by the three parameters: the
in-cage libration rate, the hopping rate, and the memory
parameter. The orientational correlation functions contain
conventional exponentially decaying contributions, oscillatory
damped sin- and cos- like contributions, and a slow algebraic
tail.
Key words:
orientational relaxation, hydrogen-bonding liquids
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